Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers

The design and gram‐scale synthesis of a cyclohexa‐1,4‐diene‐based surrogate of isobutene gas is reported. Using the highly electron‐deficient Lewis acid B(C(6)F(5))(3), application of this surrogate in the hydromethallylation of electron‐rich styrene derivatives provided sterically congested quater...

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Detalles Bibliográficos
Autores principales: Walker, Johannes C. L., Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856816/
https://www.ncbi.nlm.nih.gov/pubmed/31449730
http://dx.doi.org/10.1002/anie.201909852

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856816/
https://www.ncbi.nlm.nih.gov/pubmed/31449730
http://dx.doi.org/10.1002/anie.201909852

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