Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand

A naphthyridine‐derived expanded pincer ligand is described that can host two copper(I) centers. The proton‐responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H(2) giving an unusual butterfly‐shaped Cu(4)H(2) c...

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Detalles Bibliográficos
Autores principales: Kounalis, Errikos, Lutz, Martin, Broere, Daniël L. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856846/
https://www.ncbi.nlm.nih.gov/pubmed/31424132
http://dx.doi.org/10.1002/chem.201903724

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856846/
https://www.ncbi.nlm.nih.gov/pubmed/31424132
http://dx.doi.org/10.1002/chem.201903724

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