Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand

A naphthyridine‐derived expanded pincer ligand is described that can host two copper(I) centers. The proton‐responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H(2) giving an unusual butterfly‐shaped Cu(4)H(2) c...

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Detalles Bibliográficos
Autores principales: Kounalis, Errikos, Lutz, Martin, Broere, Daniël L. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856846/
https://www.ncbi.nlm.nih.gov/pubmed/31424132
http://dx.doi.org/10.1002/chem.201903724
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author Kounalis, Errikos
Lutz, Martin
Broere, Daniël L. J.
author_facet Kounalis, Errikos
Lutz, Martin
Broere, Daniël L. J.
author_sort Kounalis, Errikos
collection PubMed
description A naphthyridine‐derived expanded pincer ligand is described that can host two copper(I) centers. The proton‐responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H(2) giving an unusual butterfly‐shaped Cu(4)H(2) complex.
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spelling pubmed-68568462019-11-21 Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand Kounalis, Errikos Lutz, Martin Broere, Daniël L. J. Chemistry Communications A naphthyridine‐derived expanded pincer ligand is described that can host two copper(I) centers. The proton‐responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H(2) giving an unusual butterfly‐shaped Cu(4)H(2) complex. John Wiley and Sons Inc. 2019-09-24 2019-10-17 /pmc/articles/PMC6856846/ /pubmed/31424132 http://dx.doi.org/10.1002/chem.201903724 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Kounalis, Errikos
Lutz, Martin
Broere, Daniël L. J.
Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
title Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
title_full Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
title_fullStr Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
title_full_unstemmed Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
title_short Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
title_sort cooperative h(2) activation on dicopper(i) facilitated by reversible dearomatization of an “expanded pnnp pincer” ligand
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856846/
https://www.ncbi.nlm.nih.gov/pubmed/31424132
http://dx.doi.org/10.1002/chem.201903724
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AT broeredaniellj cooperativeh2activationondicopperifacilitatedbyreversibledearomatizationofanexpandedpnnppincerligand

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