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Cooperative H(2) Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an “Expanded PNNP Pincer” Ligand
A naphthyridine‐derived expanded pincer ligand is described that can host two copper(I) centers. The proton‐responsive ligand can undergo reversible partial and full dearomatization of the naphthyridine core, which enables cooperative activation of H(2) giving an unusual butterfly‐shaped Cu(4)H(2) c...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856846/ https://www.ncbi.nlm.nih.gov/pubmed/31424132 http://dx.doi.org/10.1002/chem.201903724 |