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The Parent Diarsene HAs=AsH as Side‐on Bound Ligand in an Iron Carbonyl Complex
The terminal diarsene HAs=AsH ligand attracts special interest concerning its bonding relation in comparison to its isolable relative, ethene. Herein, by the methanolysis of [{Fe(CO)(4)}As(SiMe(3))(3)] (1) the synthesis of [{Fe(CO)(4)}(η(2)‐As(2)H(2))] (2) is reported, containing a parent diarsene a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856853/ https://www.ncbi.nlm.nih.gov/pubmed/31424604 http://dx.doi.org/10.1002/anie.201909423 |