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A Neutral “Aluminocene” Sandwich Complex: η(1)‐ versus η(5)‐Coordination Modes of a Pentaarylborole with ECp* (E=Al, Ga; Cp*=C(5)Me(5))

The pentaaryl borole (Ph*C)(4)BXyl(F) [Ph*=3,5‐tBu(2)(C(6)H(3)); Xyl(F)=3,5‐(CF(3))(2)(C(6)H(3))] reacts with low‐valent Group 13 precursors AlCp* and GaCp* by two divergent routes. In the case of [AlCp*](4), the borole reacts as an oxidising agent and accepts two electrons. Structural, spectroscopi...

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Detalles Bibliográficos
Autores principales: Sindlinger, Christian P., Ruth, Paul Niklas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856865/
https://www.ncbi.nlm.nih.gov/pubmed/31390132
http://dx.doi.org/10.1002/anie.201907749