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A Neutral “Aluminocene” Sandwich Complex: η(1)‐ versus η(5)‐Coordination Modes of a Pentaarylborole with ECp* (E=Al, Ga; Cp*=C(5)Me(5))
The pentaaryl borole (Ph*C)(4)BXyl(F) [Ph*=3,5‐tBu(2)(C(6)H(3)); Xyl(F)=3,5‐(CF(3))(2)(C(6)H(3))] reacts with low‐valent Group 13 precursors AlCp* and GaCp* by two divergent routes. In the case of [AlCp*](4), the borole reacts as an oxidising agent and accepts two electrons. Structural, spectroscopi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6856865/ https://www.ncbi.nlm.nih.gov/pubmed/31390132 http://dx.doi.org/10.1002/anie.201907749 |