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Oxygen‐Depleted Calixarenes as Ligands for Molecular Models of Galactose Oxidase

A calix[4]arene ligand, in which two of the phenol functions are replaced by pyrazole units has been employed to mimic the His(2)–Tyr(2) (His: histidine, Tyr: tyrosine) ligand sphere within the active site of the galactose oxidase (GO). The calixarene backbone forces the corresponding copper(II) com...

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Detalles Bibliográficos
Autores principales: Keck, Matthias, Hoof, Santina, Herwig, Christian, Vigalok, Arkadi, Limberg, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6857004/
https://www.ncbi.nlm.nih.gov/pubmed/31441974
http://dx.doi.org/10.1002/chem.201903820