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Switching the site-selectivity of C–H activation in aryl sulfonamides containing strongly coordinating N-heterocycles

The limitations of arene C–H functionalization of aryl sulfonamides containing strongly coordinating N-heterocycles were overcome using a Rh(iii) catalyst. The site-selectivity of C–H carbenoid functionalization at the ortho position relative to either the sulfonamide or N-heterocycle directing grou...

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Detalles Bibliográficos
Autores principales: Dong, Yi, Zhang, XuePeng, Chen, Jiajing, Zou, Wenxing, Lin, Songwen, Xu, Heng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6857669/
https://www.ncbi.nlm.nih.gov/pubmed/31762973
http://dx.doi.org/10.1039/c9sc03691a