Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium

Cubic Na(3)PS(4) (c-Na(3)PS(4)), a high temperature phase of Na(3)PS(4), is successfully prepared by liquid-phase shaking from Na(2)S and P(2)S(5) in methyl acetate medium. The effects of the amount of solvents, Na(2)S and heat treatment on the formation of c-Na(3)PS(4) are carefully investigated. I...

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Detalles Bibliográficos
Autores principales: Atsunori, Matsuda, Hirotada, Gamo, Phuc, Nguyen Huu Huy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6859230/
https://www.ncbi.nlm.nih.gov/pubmed/31763471
http://dx.doi.org/10.1016/j.heliyon.2019.e02760
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author Atsunori, Matsuda
Hirotada, Gamo
Phuc, Nguyen Huu Huy
author_facet Atsunori, Matsuda
Hirotada, Gamo
Phuc, Nguyen Huu Huy
author_sort Atsunori, Matsuda
collection PubMed
description Cubic Na(3)PS(4) (c-Na(3)PS(4)), a high temperature phase of Na(3)PS(4), is successfully prepared by liquid-phase shaking from Na(2)S and P(2)S(5) in methyl acetate medium. The effects of the amount of solvents, Na(2)S and heat treatment on the formation of c-Na(3)PS(4) are carefully investigated. In addition to c-Na(3)PS(4), an unknown phase is also detected in the sample containing an excess amount of Na(2)S in the starting materials mixture.
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spelling pubmed-68592302019-11-22 Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium Atsunori, Matsuda Hirotada, Gamo Phuc, Nguyen Huu Huy Heliyon Article Cubic Na(3)PS(4) (c-Na(3)PS(4)), a high temperature phase of Na(3)PS(4), is successfully prepared by liquid-phase shaking from Na(2)S and P(2)S(5) in methyl acetate medium. The effects of the amount of solvents, Na(2)S and heat treatment on the formation of c-Na(3)PS(4) are carefully investigated. In addition to c-Na(3)PS(4), an unknown phase is also detected in the sample containing an excess amount of Na(2)S in the starting materials mixture. Elsevier 2019-11-14 /pmc/articles/PMC6859230/ /pubmed/31763471 http://dx.doi.org/10.1016/j.heliyon.2019.e02760 Text en © 2019 The Authors. Published by Elsevier Ltd. http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Article
Atsunori, Matsuda
Hirotada, Gamo
Phuc, Nguyen Huu Huy
Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium
title Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium
title_full Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium
title_fullStr Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium
title_full_unstemmed Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium
title_short Preparation of cubic Na(3)PS(4) by liquid-phase shaking in methyl acetate medium
title_sort preparation of cubic na(3)ps(4) by liquid-phase shaking in methyl acetate medium
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6859230/
https://www.ncbi.nlm.nih.gov/pubmed/31763471
http://dx.doi.org/10.1016/j.heliyon.2019.e02760
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AT phucnguyenhuuhuy preparationofcubicna3ps4byliquidphaseshakinginmethylacetatemedium

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