Relaxation Dispersion NMR to Reveal Fast Dynamics in Brønsted Acid Catalysis: Influence of Sterics and H-Bond Strength on Conformations and Substrate Hopping

[Image: see text] NMR provides both structural and dynamic information, which is key to connecting intermediates and to understanding reaction pathways. However, fast exchanging catalytic intermediates are often inaccessible by conventional NMR due its limited time resolution. Here, we show the comb...

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Detalles Bibliográficos
Autores principales: Lokesh, N., Hioe, Johnny, Gramüller, Johannes, Gschwind, Ruth M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6863621/
https://www.ncbi.nlm.nih.gov/pubmed/31545037
http://dx.doi.org/10.1021/jacs.9b07841

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6863621/
https://www.ncbi.nlm.nih.gov/pubmed/31545037
http://dx.doi.org/10.1021/jacs.9b07841

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