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Improved Access to Chiral Tetranaphthoazepinium-Based Organocatalysts Using Aqueous Ammonia as Nitrogen Source

The class of 3,3′-diaryl substituted tetranaphthobisazepinium bromides has found wide application as highly efficient C(2)-symmetrical phase-transfer catalysts (PTCs, Maruoka type catalysts). Unfortunately, the synthesis requires a large number of steps and hampers the build-up of catalyst libraries...

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Detalles Bibliográficos
Autores principales: Manaprasertsak, Auraya, Tharamak, Sorachat, Schedl, Christina, Roller, Alexander, Widhalm, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6864439/
https://www.ncbi.nlm.nih.gov/pubmed/31731415
http://dx.doi.org/10.3390/molecules24213844