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Synthesis, Spectroscopy and Electrochemistry in Relation to DFT Computed Energies of Ferrocene- and Ruthenocene-Containing β-Diketonato Iridium(III) Heteroleptic Complexes. Structure of [(2-Pyridylphenyl)(2)Ir(RcCOCHCOCH(3)]
A series of new ferrocene- and ruthenocene-containing iridium(III) heteroleptic complexes of the type [(ppy)(2)Ir(RCOCHCOR′)], with ppy = 2-pyridylphenyl, R = Fc = Fe(II)(η(5)-C(5)H(4))(η(5)-C(5)H(5)) and R′ = CH(3) (1) or Fc (2), as well as R = Rc = Ru(II)(η(5)-C(5)H(4))(η(5)-C(5)H(5)) and R′ = CH(...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6864483/ https://www.ncbi.nlm.nih.gov/pubmed/31671705 http://dx.doi.org/10.3390/molecules24213923 |