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Reaction Mechanism of Li and Mg Carbenoid Cyclopropanations: Metal-π and σ Interactions
[Image: see text] The mechanism of the reaction of lithium and magnesium carbenoids with ethylene to give cyclopropane has been explained in detail in all the steps at the G4 level of theory. We explored the lithium and magnesium interaction toward π(C=C) and σ(C–C) bonds in the reactants and the pr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6868892/ https://www.ncbi.nlm.nih.gov/pubmed/31763569 http://dx.doi.org/10.1021/acsomega.9b02905 |