Redox Tuning via Ligand-Induced Geometric Distortions at a YMn(3)O(4) Cubane Model of the Biological Oxygen Evolving Complex

[Image: see text] The function of proteins involved in electron transfer is dependent on cofactors attaining the necessary reduction potentials. We establish a mode of cluster redox tuning through steric pressure on a synthetic model related to Photosystem II. Resembling the cuboidal [CaMn(3)O(4)] s...

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Detalles Bibliográficos
Autores principales: Lee, Heui Beom, Agapie, Theodor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6876925/
https://www.ncbi.nlm.nih.gov/pubmed/31095368
http://dx.doi.org/10.1021/acs.inorgchem.9b00510

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6876925/
https://www.ncbi.nlm.nih.gov/pubmed/31095368
http://dx.doi.org/10.1021/acs.inorgchem.9b00510

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