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Redox Tuning via Ligand-Induced Geometric Distortions at a YMn(3)O(4) Cubane Model of the Biological Oxygen Evolving Complex
[Image: see text] The function of proteins involved in electron transfer is dependent on cofactors attaining the necessary reduction potentials. We establish a mode of cluster redox tuning through steric pressure on a synthetic model related to Photosystem II. Resembling the cuboidal [CaMn(3)O(4)] s...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6876925/ https://www.ncbi.nlm.nih.gov/pubmed/31095368 http://dx.doi.org/10.1021/acs.inorgchem.9b00510 |