Cargando…

Probing the Hydrogenation of Vinyl Sulfoxides Using para-Hydrogen

[Image: see text] Vinyl sulfoxides are an important functional group used in a wide range of organic transformations. Here, we use [IrCl(COD)(IMes)] where IMes = 1,3-bis(2,4,6-trimethyl-phenyl)imidazole-2-ylidene and COD = cis,cis-1,5-cyclooctadiene to rapidly hydrogenate phenylvinylsulfoxide. We us...

Descripción completa

Detalles Bibliográficos
Autores principales: Tickner, Ben J., Parker, Rachel R., Whitwood, Adrian C., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6880776/
https://www.ncbi.nlm.nih.gov/pubmed/31787798
http://dx.doi.org/10.1021/acs.organomet.9b00610