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Sources of Nonlinear van’t Hoff Temperature Dependence in High-Performance Liquid Chromatography

[Image: see text] In HPLC, the nonlinear behavior of the retention factor k′ with temperature (dependence of ln k′ on 1/T) can be attributed to the multiple interactions of a unique analyte in the separation process and/or to the existence in solution of multiple forms of the analyte (also leading t...

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Detalles Bibliográficos
Autores principales: Tanase, Maria, Soare, Andreia, David, Victor, Moldoveanu, Serban C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6882149/
https://www.ncbi.nlm.nih.gov/pubmed/31788613
http://dx.doi.org/10.1021/acsomega.9b02689