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Low-Melting Manganese(II)-Based Ionic Liquids: Syntheses, Structures, Properties and Influence of Trace Impurities

The synthesis of more than 10 new magnetic ionic liquids with [MnX(4)](2−) anions, X = Cl, NCS, NCO, is presented. Detailed structural information through single-crystal X-ray diffraction is given for (DMDIm)[Mn(NCS)(4)], (BnEt(3)N)(2)[Mn(NCS)(4)], and {(Ph(3)P)(2)N}(2)[Mn(NCO(4))]·0.6H(2)O, respect...

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Detalles Bibliográficos
Autores principales: Peppel, Tim, Geppert-Rybczyńska, Monika, Neise, Christin, Kragl, Udo, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6888301/
https://www.ncbi.nlm.nih.gov/pubmed/31731826
http://dx.doi.org/10.3390/ma12223764