Sulphide as a leaving group: highly stereoselective bromination of alkyl phenyl sulphides

A conceptionally novel nucleophilic substitution approach to synthetically important alkyl bromides is presented. Using molecular bromine (Br(2)), readily available secondary benzyl and tertiary alkyl phenyl sulphides are converted into the corresponding bromides under exceptionally mild, acid- and...

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Detalles Bibliográficos
Autores principales: Canestrari, Daniele, Cioffi, Caterina, Biancofiore, Ilaria, Lancianesi, Stefano, Ghisu, Lorenza, Ruether, Manuel, O'Brien, John, Adamo, Mauro F. A., Ibrahim, Hasim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6889150/
https://www.ncbi.nlm.nih.gov/pubmed/31827746
http://dx.doi.org/10.1039/c9sc03560e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6889150/
https://www.ncbi.nlm.nih.gov/pubmed/31827746
http://dx.doi.org/10.1039/c9sc03560e

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