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Structural and solvent control over activation parameters for a pair of retro Diels-Alder reactions

We report the temperature dependent NMR of two Diels-Alder adducts of furan: one formed with maleic anhydride and the other with N-methylmaleimide. These adducts are the products of so-called ‘click’ reactions, widely valued for providing simple, reliable, and robust reactivity. Under our experiment...

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Detalles Bibliográficos
Autores principales: Widstrom, Andrea L., Lear, Benjamin J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6892874/
https://www.ncbi.nlm.nih.gov/pubmed/31797942
http://dx.doi.org/10.1038/s41598-019-54156-4