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Crystal structure of dicarbonyl[μ(2)-methylenebis(diphenylphosphane)-κ(2) P:P′][μ(2)-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)–dichloromethane–toluene (1/1/2), [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(2,4,5-C(6)H(2)Me(3))=CH)Pt(PPh(3))]
The title compound, [FePt(C(12)H(12)O)(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)]·2C(7)H(8)·CH(2)Cl(2) or [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(2,4,5-C(6)H(2)Me(3))=CH)Pt(PPh(3))], represents an example of a diphosphane-bridged heterobimetallic dimetallacyclopentenone complex resulting from a bimetallic activatio...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895934/ https://www.ncbi.nlm.nih.gov/pubmed/31871755 http://dx.doi.org/10.1107/S2056989019015573 |