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Crystal structure of dicarbon­yl[μ(2)-methyl­enebis(di­phenyl­phosphane)-κ(2) P:P′][μ(2)-2-(2,4,5-tri­methyl­phen­yl)-3-oxoprop-1-ene-1,3-di­yl](tri­phenyl­phosphane-κP)ironplatinum(Fe—Pt)–di­chloro­methane–toluene (1/1/2), [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(2,4,5-C(6)H(2)Me(3))=CH)Pt(PPh(3))]

The title compound, [FePt(C(12)H(12)O)(C(18)H(15)P)(C(25)H(22)P(2))(CO)(2)]·2C(7)H(8)·CH(2)Cl(2) or [(OC)(2)Fe(μ-dppm)(μ-C(=O)C(2,4,5-C(6)H(2)Me(3))=CH)Pt(PPh(3))], represents an example of a diphosphane-bridged heterobimetallic dimetalla­cyclo­pentenone complex resulting from a bimetallic activatio...

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Detalles Bibliográficos
Autores principales: Brieger, Lukas, Jourdain, Isabelle, Knorr, Michael, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895934/
https://www.ncbi.nlm.nih.gov/pubmed/31871755
http://dx.doi.org/10.1107/S2056989019015573