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Reversible Encapsulation of Xenon and CH(2)Cl(2) in a Solid‐State Molecular Organometallic Framework (Guest@SMOM)

Reversible encapsulation of CH(2)Cl(2) or Xe in a non‐porous solid‐state molecular organometallic framework of [Rh(Cy(2)PCH(2)PCy(2))(NBD)][BAr(F) (4)] occurs in single‐crystal to single‐crystal transformations. These processes are probed by solid‐state NMR spectroscopy, including (129)Xe SSNMR. Non...

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Detalles Bibliográficos
Autores principales: Martínez‐Martínez, Antonio J., Rees, Nicholas H., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899477/
https://www.ncbi.nlm.nih.gov/pubmed/31539184
http://dx.doi.org/10.1002/anie.201910539