Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

A copper‐catalyzed silylation of propargyl dichlorides was developed to access chloro‐substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro‐substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol....

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Detalles Bibliográficos
Autores principales: Liu, Zheng‐Li, Yang, Chao, Xue, Qi‐Yan, Zhao, Meng, Shan, Cui‐Cui, Xu, Yun‐He, Loh, Teck‐Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899605/
https://www.ncbi.nlm.nih.gov/pubmed/31532868
http://dx.doi.org/10.1002/anie.201908343

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899605/
https://www.ncbi.nlm.nih.gov/pubmed/31532868
http://dx.doi.org/10.1002/anie.201908343

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