Structural Mimics of Acetylene Hydratase: Tungsten Complexes Capable of Intramolecular Nucleophilic Attack on Acetylene

Bioinspired complexes employing the ligands 6‐tert‐butylpyridazine‐3‐thione (SPn) and pyridine‐2‐thione (SPy) were synthesized and fully characterized to mimic the tungstoenzyme acetylene hydratase (AH). The complexes [W(CO)(C(2)H(2))(CHCH‐SPy)(SPy)] (4) and [W(CO)(C(2)H(2))(CHCH‐SPn)(SPn)] (5) were...

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Detalles Bibliográficos
Autores principales: Vidovič, Carina, Peschel, Lydia M., Buchsteiner, Michael, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899645/
https://www.ncbi.nlm.nih.gov/pubmed/31603595
http://dx.doi.org/10.1002/chem.201903264

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899645/
https://www.ncbi.nlm.nih.gov/pubmed/31603595
http://dx.doi.org/10.1002/chem.201903264

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