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Structural Mimics of Acetylene Hydratase: Tungsten Complexes Capable of Intramolecular Nucleophilic Attack on Acetylene
Bioinspired complexes employing the ligands 6‐tert‐butylpyridazine‐3‐thione (SPn) and pyridine‐2‐thione (SPy) were synthesized and fully characterized to mimic the tungstoenzyme acetylene hydratase (AH). The complexes [W(CO)(C(2)H(2))(CHCH‐SPy)(SPy)] (4) and [W(CO)(C(2)H(2))(CHCH‐SPn)(SPn)] (5) were...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899645/ https://www.ncbi.nlm.nih.gov/pubmed/31603595 http://dx.doi.org/10.1002/chem.201903264 |