Titanium(III)‐Catalyzed Reductive Decyanation of Geminal Dinitriles by a Non‐Free‐Radical Mechanism

A titanium‐catalyzed mono‐decyanation of geminal dinitriles is reported. The reaction proceeds under mild conditions, tolerates numerous functional groups, and can be applied to quaternary malononitriles. A corresponding desulfonylation is demonstrated as well. Mechanistic experiments support a cata...

Descripción completa

Detalles Bibliográficos
Autores principales: Weweler, Jens, Younas, Sara L., Streuff, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899653/
https://www.ncbi.nlm.nih.gov/pubmed/31513329
http://dx.doi.org/10.1002/anie.201908372

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899653/
https://www.ncbi.nlm.nih.gov/pubmed/31513329
http://dx.doi.org/10.1002/anie.201908372

Ejemplares similares