Cargando…

N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds

N‐heterocyclic olefins (NHOs), relatives of N‐heterocyclic carbenes (NHCs), exhibit high nucleophilicity and soft Lewis basic character. To investigate their π‐electron donating ability, NHOs were attached to triarylborane π‐acceptors (A) giving donor (D)–π–A compounds 1–3. In addition, an enamine π...

Descripción completa

Detalles Bibliográficos
Autores principales: He, Jiang, Rauch, Florian, Friedrich, Alexandra, Sieh, Daniel, Ribbeck, Tatjana, Krummenacher, Ivo, Braunschweig, Holger, Finze, Maik, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899742/
https://www.ncbi.nlm.nih.gov/pubmed/31471986
http://dx.doi.org/10.1002/chem.201903118