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N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds
N‐heterocyclic olefins (NHOs), relatives of N‐heterocyclic carbenes (NHCs), exhibit high nucleophilicity and soft Lewis basic character. To investigate their π‐electron donating ability, NHOs were attached to triarylborane π‐acceptors (A) giving donor (D)–π–A compounds 1–3. In addition, an enamine π...
Autores principales: | He, Jiang, Rauch, Florian, Friedrich, Alexandra, Sieh, Daniel, Ribbeck, Tatjana, Krummenacher, Ivo, Braunschweig, Holger, Finze, Maik, Marder, Todd B. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899742/ https://www.ncbi.nlm.nih.gov/pubmed/31471986 http://dx.doi.org/10.1002/chem.201903118 |
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