Cargando…

Di‐tert‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer

While tetrahedranes as a family are scarce, neutral heteroatomic species are all but unknown, with the only reported example being AsP(3). Herein, we describe the isolation of a neutral heteroatomic X(2)Y(2) molecular tetrahedron (X, Y=p‐block elements), which also is the long‐sought‐after free phos...

Descripción completa

Detalles Bibliográficos
Autores principales: Hierlmeier, Gabriele, Coburger, Peter, Bodensteiner, Michael, Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899750/
https://www.ncbi.nlm.nih.gov/pubmed/31591760
http://dx.doi.org/10.1002/anie.201910505