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Di‐tert‐butyldiphosphatetrahedrane: Catalytic Synthesis of the Elusive Phosphaalkyne Dimer
While tetrahedranes as a family are scarce, neutral heteroatomic species are all but unknown, with the only reported example being AsP(3). Herein, we describe the isolation of a neutral heteroatomic X(2)Y(2) molecular tetrahedron (X, Y=p‐block elements), which also is the long‐sought‐after free phos...
Autores principales: | Hierlmeier, Gabriele, Coburger, Peter, Bodensteiner, Michael, Wolf, Robert |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899750/ https://www.ncbi.nlm.nih.gov/pubmed/31591760 http://dx.doi.org/10.1002/anie.201910505 |
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