Light‐Mediated Formal Radical Deoxyfluorination of Tertiary Alcohols through Selective Single‐Electron Oxidation with TEDA(2+.)

The synthesis of tertiary alkyl fluorides through a formal radical deoxyfluorination process is described herein. This light‐mediated, catalyst‐free methodology is fast and broadly applicable allowing for the preparation of C−F bonds from (hetero)benzylic, propargylic, and non‐activated tertiary alc...

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Detalles Bibliográficos
Autores principales: Aguilar Troyano, Francisco José, Ballaschk, Frederic, Jaschinski, Marcel, Özkaya, Yasemin, Gómez‐Suárez, Adrián
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899844/
https://www.ncbi.nlm.nih.gov/pubmed/31452265
http://dx.doi.org/10.1002/chem.201903702

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899844/
https://www.ncbi.nlm.nih.gov/pubmed/31452265
http://dx.doi.org/10.1002/chem.201903702

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