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Light‐Mediated Formal Radical Deoxyfluorination of Tertiary Alcohols through Selective Single‐Electron Oxidation with TEDA(2+.)
The synthesis of tertiary alkyl fluorides through a formal radical deoxyfluorination process is described herein. This light‐mediated, catalyst‐free methodology is fast and broadly applicable allowing for the preparation of C−F bonds from (hetero)benzylic, propargylic, and non‐activated tertiary alc...
Autores principales: | Aguilar Troyano, Francisco José, Ballaschk, Frederic, Jaschinski, Marcel, Özkaya, Yasemin, Gómez‐Suárez, Adrián |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899844/ https://www.ncbi.nlm.nih.gov/pubmed/31452265 http://dx.doi.org/10.1002/chem.201903702 |
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