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Perfluoro Alkyl Hypofluorites and Peroxides Revisited

A more convenient synthesis of the perfluoro alkyl hypofluorite (F(3)C)(3)COF as well as the hitherto unknown (C(2)F(5))(F(3)C)(2)COF compound is reported. Both hypofluorites can be prepared by use of the corresponding tertiary alcohols R(F)OH and elemental fluorine in the presence of CsF. An approp...

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Detalles Bibliográficos
Autores principales: Nissen, Jan H., Drews, Thomas, Schröder, Benjamin, Beckers, Helmut, Steinhauer, Simon, Riedel, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899984/
https://www.ncbi.nlm.nih.gov/pubmed/31518021
http://dx.doi.org/10.1002/chem.201903620