Stereoselective Thioconjugation by Photoinduced Thiol‐ene Coupling Reactions of Hexo‐ and Pentopyranosyl d‐ and l‐Glycals at Low‐Temperature—Reactivity and Stereoselectivity Study

A comprehensive optimization and mechanistic study on the photoinduced hydrothiolation of different d‐ and l‐ hexo‐ and pentoglycals with various thiols was performed, at the temperature range of RT to −120 °C. Addition of thiols onto 2‐substituted hexoglycals proceeded with complete 1,2‐cis‐α‐stere...

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Detalles Bibliográficos
Autores principales: Kelemen, Viktor, Bege, Miklós, Eszenyi, Dániel, Debreczeni, Nóra, Bényei, Attila, Stürzer, Tobias, Herczegh, Pál, Borbás, Anikó
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900028/
https://www.ncbi.nlm.nih.gov/pubmed/31368604
http://dx.doi.org/10.1002/chem.201903095

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900028/
https://www.ncbi.nlm.nih.gov/pubmed/31368604
http://dx.doi.org/10.1002/chem.201903095

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