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Stereoselective Thioconjugation by Photoinduced Thiol‐ene Coupling Reactions of Hexo‐ and Pentopyranosyl d‐ and l‐Glycals at Low‐Temperature—Reactivity and Stereoselectivity Study
A comprehensive optimization and mechanistic study on the photoinduced hydrothiolation of different d‐ and l‐ hexo‐ and pentoglycals with various thiols was performed, at the temperature range of RT to −120 °C. Addition of thiols onto 2‐substituted hexoglycals proceeded with complete 1,2‐cis‐α‐stere...
Autores principales: | Kelemen, Viktor, Bege, Miklós, Eszenyi, Dániel, Debreczeni, Nóra, Bényei, Attila, Stürzer, Tobias, Herczegh, Pál, Borbás, Anikó |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900028/ https://www.ncbi.nlm.nih.gov/pubmed/31368604 http://dx.doi.org/10.1002/chem.201903095 |
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