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A Highly Warped Heptagon‐Containing sp(2) Carbon Scaffold via Vinylnaphthyl π‐Extension
A new strategy is demonstrated for the synthesis of warped, negatively curved, all‐sp(2)‐carbon π‐scaffolds. Multifold C−C coupling reactions are used to transform a polyaromatic borinic acid into a saddle‐shaped polyaromatic hydrocarbon (2) bearing two heptagonal rings. Notably, this Schwarzite sub...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900032/ https://www.ncbi.nlm.nih.gov/pubmed/31507020 http://dx.doi.org/10.1002/anie.201909975 |