A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO(2) Nanoparticles

Here we provide evidence that the formation of PuO(2) nanoparticles from oxidized Pu(VI) under alkaline conditions proceeds through the formation of an intermediate Pu(V) solid phase, similar to NH(4)PuO(2)CO(3), which is stable over a period of several months. For the first time, state‐of‐the‐art e...

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Detalles Bibliográficos
Autores principales: Kvashnina, Kristina O., Romanchuk, Anna Yu., Pidchenko, Ivan, Amidani, Lucia, Gerber, Evgeny, Trigub, Alexander, Rossberg, Andre, Weiss, Stephan, Popa, Karin, Walter, Olaf, Caciuffo, Roberto, Scheinost, Andreas C., Butorin, Sergei M., Kalmykov, Stepan N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900038/
https://www.ncbi.nlm.nih.gov/pubmed/31621992
http://dx.doi.org/10.1002/anie.201911637

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900038/
https://www.ncbi.nlm.nih.gov/pubmed/31621992
http://dx.doi.org/10.1002/anie.201911637

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