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Donor Strengths Determination of Pnictogen and Chalcogen Ligands by the Huynh Electronic Parameter and Its Correlation to Sigma Hammett Constants

The suitability and accuracy of the Huynh electronic parameter (HEP) was further tested to reveal remote substituent effects in pyridines, which are located five or six bonds away from the reporter probe. These values show an excellent correlation to Hammett σ‐constants of the respective substituent...

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Detalles Bibliográficos
Autores principales: Teng, Qiaoqiao, Ng, Ping Siang, Leung, Jia Nuo, Huynh, Han Vinh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900057/
https://www.ncbi.nlm.nih.gov/pubmed/31414703
http://dx.doi.org/10.1002/chem.201902795