Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions

A metal‐free, intermolecular syn‐addition of hexamethyldisilane across simple alkenes is reported. The catalytic cycle is initiated and propagated by the transfer of a methyl group from the disilane to a silylium‐ion‐like intermediate, corresponding to the (re)generation of the silylium‐ion catalyst...

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Detalles Bibliográficos
Autores principales: Wu, Qian, Roy, Avijit, Irran, Elisabeth, Qu, Zheng‐Wang, Grimme, Stefan, Klare, Hendrik F. T., Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900109/
https://www.ncbi.nlm.nih.gov/pubmed/31566863
http://dx.doi.org/10.1002/anie.201911282

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900109/
https://www.ncbi.nlm.nih.gov/pubmed/31566863
http://dx.doi.org/10.1002/anie.201911282

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