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Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions

A metal‐free, intermolecular syn‐addition of hexamethyldisilane across simple alkenes is reported. The catalytic cycle is initiated and propagated by the transfer of a methyl group from the disilane to a silylium‐ion‐like intermediate, corresponding to the (re)generation of the silylium‐ion catalyst...

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Detalles Bibliográficos
Autores principales:	Wu, Qian, Roy, Avijit, Irran, Elisabeth, Qu, Zheng‐Wang, Grimme, Stefan, Klare, Hendrik F. T., Oestreich, Martin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900109/ https://www.ncbi.nlm.nih.gov/pubmed/31566863 http://dx.doi.org/10.1002/anie.201911282

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