Dissipative Catalysis with a Molecular Machine

We report on catalysis by a fuel‐induced transient state of a synthetic molecular machine. A [2]rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations is converted between catalytically inactive and active states by pulses of a chemical fuel (trichloroacetic acid), whic...

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Detalles Bibliográficos
Autores principales: Biagini, Chiara, Fielden, Stephen D. P., Leigh, David A., Schaufelberger, Fredrik, Di Stefano, Stefano, Thomas, Dean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900173/
https://www.ncbi.nlm.nih.gov/pubmed/31111628
http://dx.doi.org/10.1002/anie.201905250

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900173/
https://www.ncbi.nlm.nih.gov/pubmed/31111628
http://dx.doi.org/10.1002/anie.201905250

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