Transient Phosphenium and Arsenium Ions versus Stable Stibenium and Bismuthenium Ions

Fluoride abstraction from bis‐m‐terphenylelement fluorides (2,6‐Mes(2)C(6)H(3))(2)EF (E=P, As) generated the highly reactive phosphenium ion [(2,6‐Mes(2)C(6)H(3))(2)P](+) and the arsenium ion [(2,6‐Mes(2)C(6)H(3))(2)As](+), which immediately underwent intramolecular electrophilic substitution and fo...

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Detalles Bibliográficos
Autores principales: Olaru, Marian, Duvinage, Daniel, Lork, Enno, Mebs, Stefan, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900177/
https://www.ncbi.nlm.nih.gov/pubmed/31404472
http://dx.doi.org/10.1002/chem.201902520

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900177/
https://www.ncbi.nlm.nih.gov/pubmed/31404472
http://dx.doi.org/10.1002/chem.201902520

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