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Transient Phosphenium and Arsenium Ions versus Stable Stibenium and Bismuthenium Ions
Fluoride abstraction from bis‐m‐terphenylelement fluorides (2,6‐Mes(2)C(6)H(3))(2)EF (E=P, As) generated the highly reactive phosphenium ion [(2,6‐Mes(2)C(6)H(3))(2)P](+) and the arsenium ion [(2,6‐Mes(2)C(6)H(3))(2)As](+), which immediately underwent intramolecular electrophilic substitution and fo...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900177/ https://www.ncbi.nlm.nih.gov/pubmed/31404472 http://dx.doi.org/10.1002/chem.201902520 |