HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols

[Image: see text] A silver-tetrafluoroborate- or HBF(4)-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.

Detalles Bibliográficos
Autores principales: Rank, Christian K., Özkaya, Bünyamin, Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900263/
https://www.ncbi.nlm.nih.gov/pubmed/31429294
http://dx.doi.org/10.1021/acs.orglett.9b02470
Descripción
Sumario:[Image: see text] A silver-tetrafluoroborate- or HBF(4)-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.

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