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HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols

[Image: see text] A silver-tetrafluoroborate- or HBF(4)-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.

Detalles Bibliográficos
Autores principales: Rank, Christian K., Özkaya, Bünyamin, Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900263/
https://www.ncbi.nlm.nih.gov/pubmed/31429294
http://dx.doi.org/10.1021/acs.orglett.9b02470
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author Rank, Christian K.
Özkaya, Bünyamin
Patureau, Frederic W.
author_facet Rank, Christian K.
Özkaya, Bünyamin
Patureau, Frederic W.
author_sort Rank, Christian K.
collection PubMed
description [Image: see text] A silver-tetrafluoroborate- or HBF(4)-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.
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spelling pubmed-69002632019-12-10 HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols Rank, Christian K. Özkaya, Bünyamin Patureau, Frederic W. Org Lett [Image: see text] A silver-tetrafluoroborate- or HBF(4)-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion. American Chemical Society 2019-08-20 2019-09-06 /pmc/articles/PMC6900263/ /pubmed/31429294 http://dx.doi.org/10.1021/acs.orglett.9b02470 Text en Copyright © 2019 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Rank, Christian K.
Özkaya, Bünyamin
Patureau, Frederic W.
HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols
title HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols
title_full HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols
title_fullStr HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols
title_full_unstemmed HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols
title_short HBF(4)- and AgBF(4)-Catalyzed ortho-Alkylation of Diarylamines and Phenols
title_sort hbf(4)- and agbf(4)-catalyzed ortho-alkylation of diarylamines and phenols
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6900263/
https://www.ncbi.nlm.nih.gov/pubmed/31429294
http://dx.doi.org/10.1021/acs.orglett.9b02470
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