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Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

Aromaticity generally describes a cyclic structure composed of sp(2)-hybridized carbon or hetero atoms with remarkable stability and unique reactivity. The doping of even one sp(3)-hybridized atom often damages the aromaticity due to the interrupted electron conjugation. Here we demonstrate the occu...

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Detalles Bibliográficos
Autores principales: Xiao, Kui, Zhao, Yu, Zhu, Jun, Zhao, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6904676/
https://www.ncbi.nlm.nih.gov/pubmed/31822673
http://dx.doi.org/10.1038/s41467-019-13663-8