Acyl radical to rhodacycle addition and cyclization relay to access butterfly flavylium fluorophores

Transition metal-catalyzed C–H activation and radical reactions are two versatile strategies to construct diverse organic skeletons. Here we show the construction of a class of flavylium fluorophores via the merge of radical chemistry and C–H activation starting from (hetero)aryl ketones and alkynes...

Descripción completa

Detalles Bibliográficos
Autores principales: Yin, Jiangliang, Zhang, Yuming, Li, Jian, Zhu, Lei, Lan, Yu, You, Jingsong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6906420/
https://www.ncbi.nlm.nih.gov/pubmed/31827100
http://dx.doi.org/10.1038/s41467-019-13611-6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6906420/
https://www.ncbi.nlm.nih.gov/pubmed/31827100
http://dx.doi.org/10.1038/s41467-019-13611-6

Ejemplares similares