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Nickel/Brønsted Acid-Catalyzed Chemo- and Enantioselective Intermolecular Hydroamination of Conjugated Dienes

A novel nickel/Brønsted acid-catalyzed asymmetric hydroamination of acyclic 1,3-dienes has been established. A wide array of primary and secondary amines can be transformed into allylic amines with high yields and high enantioselectivities under very mild conditions. Moreover, our method is compatib...

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Detalles Bibliográficos
Autores principales: Long, Jiao, Wang, Peng, Wang, Wang, Li, Yuqiang, Yin, Guoyin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6906649/
https://www.ncbi.nlm.nih.gov/pubmed/31812807
http://dx.doi.org/10.1016/j.isci.2019.11.008