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C–H Halogenation of Pyridyl Sulfides Avoiding the Sulfur Oxidation: A Direct Catalytic Access to Sulfanyl Polyhalides and Polyaromatics

[Image: see text] Palladium-catalyzed oxidative C–H halogenation and acetoxylation reactions of S-unprotected sulfides, selectively directed by pyridinyl groups, allows the formation of C–X bonds (X = I, Br, Cl, OAc) by using simple halosuccinimide or phenyliodine diacetate (PIDA) oxidants. The unde...

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Detalles Bibliográficos
Autores principales: Guilbaud, Johan, Selmi, Awatef, Kammoun, Majed, Contal, Sylvie, Montalbetti, Christian, Pirio, Nadine, Roger, Julien, Hierso, Jean-Cyrille
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6906771/
https://www.ncbi.nlm.nih.gov/pubmed/31858029
http://dx.doi.org/10.1021/acsomega.9b01636